摘要
以ＳＰＡＮ８０作为乳化剂，偶氮二异丁基脒盐酸盐（ＡＩＢＡ）作为引发剂，进行丙烯酰胺－Ｎ，Ｎ－二甲基－Ｎ－丁基－Ｎ－甲基丙烯酸乙酯溴化铵（ＤＢＭＡ）反相乳液共聚合反应。研究了单体配比、乳化剂用量、引发剂用量及反应条件等对聚合反应动力学的影响，考察了该共聚物乳液的流变性能。
In this paper, selecting SPAN 80 as emulsifier, azobis(isobutylamidine hydrochloride)(AIBA) as initiator, the inverse emulsion copolymerization of acrylamide and N dimethyl N butyl N ethylmethacrylate ammonium bromine(DBMA) was developed. The effects of monomer′s ratio, emulsifier content, initiator content and reaction condition etc. on the polymerization kinetics were studied, the rheological properties of the copolymer emulsion were investigated.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1999年第2期47-49,54,共4页
Polymer Materials Science & Engineering
关键词
丙烯酰胺
动力学
乳液聚合
聚酰胺
DBMA
acrylamide, inverse emulsion, reaction kinetics, inverse emulsion polymerization, functional monomer
