七环[7.6.1.0^(2,8).0^(3,7).0^(4,13).0^(6,12).0^(10,15)]十六烷-11,14-二酮的合成研究

The research of synthetic method of heptacyclo [7.6.1.0～(2,8).0～(3,7).0～(4,13).0～(6,12).0～(10,15)]hexadecane-11,14-dione

以环戊二烯和对苯醌为原料,经过Diels-Alder反应、碱催化烯醇化、卟啉催化氧化、还原反应、[2+2]光反应合成了七环[7.6.1.02,8.03,7.04,13.06,12.010,15]十六烷-11,14-二酮。并通过对溶剂、催化剂、氧化剂及光反应条件的探讨,优化了反应条件。采用熔点测定、核磁共振氢谱、碳谱和红外光谱等手段对各步产物进行了表征。

Heptacyclo [ 7. 6. 1. 0^2,8. 0^3,7. 0^4 ,13.0^6,12.0 ^10,15 ]hexadecane - 11,14 - dione was synthesized from cyclopentadiene and 1,4-Benzoquinone by Diels-Alder reaction, enolization, porphyrin-catalyzed oxidation, reduction, [ 2 ＋ 2 ] photo-cyclo addition. The optimal synthetic conditions were obtained by research of the solvent type, catalyzer, oxidant and the characteristic of lamp. The product was characterized by melting point, IR spectra, ^1 H NMR and ^13C NMR spectra.