摘要
A novel four-way combining catalysts containing double layers was applied to simultaneously remove four kinds of exhaust pollutants （NOx, CO, HC and PM） emitted from diesel engine. The four-way catalysts were characterized using scanning electron microscope （SEM） and Ultraviolet visible diffuse reflectance spectroscopy （UV-Vis DRS）. Their catalytic performances were evaluated by temperature-programmed reaction technology. The double layer catalysts could effectively remove the four main pollutants. The highest catalytic activity was given by the two-layered catalysts of La0.6 K0.4CoO3/Al2O3 and W/HZSM-5. Under the simulated exhaust gases conditions, the peak temperature of the soot combustion was 421℃, the maximal conversion of NO to N2 was 74%, the temperature of the HC total conversion was 357℃, and the maximum conversion ratio of CO was 99%.
A novel four-way combining catalysts containing double layers was applied to simultaneously remove four kinds of exhaust pollutants （NOx, CO, HC and PM） emitted from diesel engine. The four-way catalysts were characterized using scanning electron microscope （SEM） and Ultraviolet visible diffuse reflectance spectroscopy （UV-Vis DRS）. Their catalytic performances were evaluated by temperature-programmed reaction technology. The double layer catalysts could effectively remove the four main pollutants. The highest catalytic activity was given by the two-layered catalysts of La0.6 K0.4CoO3/Al2O3 and W/HZSM-5. Under the simulated exhaust gases conditions, the peak temperature of the soot combustion was 421℃, the maximal conversion of NO to N2 was 74%, the temperature of the HC total conversion was 357℃, and the maximum conversion ratio of CO was 99%.
基金
supported by the Hi-Tech Research and Development Program (863) of China (No.SQ2009AA06Z313)
the National Natural Science Foundation of China (No. 20803093,20833011)
the Doctor Selected Foundation for the University of State Education Ministry of China (No. 200804251016)
the Beijing Outstanding Ph.D Thesis Foundation (No. YB20091141401)
