环四亚甲基四硝胺热分解机理的一种数学辨识方法

A MATHEMATICAL IDENTIFICATION METHOD FOR THE MECHANISM OF THERMAL DECOMPOSITION OF CYCLOTETRAMETHYLENE TETRANITRAMINE

本文根据质量守恒原理及线性代数方法提出了一种环四亚甲基四硝胺(HMX)热分解机理的数学辨识方法,此法可以辨识HMX热分解反应机理,同时可以求出HMX热分解各产物的生成速度及各反应的约化速度,此法对其他反应体系亦适用。

Using means provided by linear algebra, a method for the mathematical identification of the thermal decomposition mechanism of cyclotetramethy-lene let rani tramine ( HMX ) i s deduced, based on the principle of conservation of mass. By this msthod tne thermal decomposition mechanism of HMX can be identified,as well as ths rates of formation of HMX decomposition products and the reduced rates of the various reactions of HMX decomposition can be calculated. The method is alco suitable for other reaction systems.