具有3维阳离子超分子框架结构的(4,4'-BipyH_2)_2(FeCl_4)_3·Cl的水热合成和晶体结构(英文)

HYDROTHERMAL SYNTHESIS AND CRYSTAL STRUCTURE OF(4,4'-BipyH_2)_2(FeCl_4)_3·Cl WITH A 3-D CATIONIC SUPRAMOLECULAR FRAMEWORK

通过水热反应合成了一种新的具有3维阳离子超分子框架结构的化合物(4,4'-BipyH2)2(FeCl4)3Cl(1),并对该化合物进行了X-射线单晶结构表征。该化合物具有孤立结构特征,在分子中含有4,4'-BipyH2,FeCl4和氯离子。它们通过氢键形成3维阳离子超分子框架结构。(FeCl4)-离子位于该超分子框架结构的空隙中。

A new compound with a three-dimensional cationic supramolecular framework,（4,4＇-BipyH2）2（FeCl4）3Cl（1）, has been synthesized via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction.The crystal structure analysis reveals that the title compound features an isolated structure, based on 4,4＇-BipyH2 moieties, Clanions and an iron atom terminally bound by four chlorine atoms.The 4,4＇-BipyH2 moieties, Clanions and（FeCl4）-anions are interconnected via hydrogen bonds to form a 3-D cationic supramolecular framework with some（FeCl4）-anions residing in the voids of the cationic supramolecular framework.