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Electrochemical behavior and the determination of methyl jasmonate 被引量:3

Electrochemical behavior and the determination of methyl jasmonate
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摘要 In this work,the electrochemical behavior of methyl jasmonate(MeJA)on a glassy carbon electrode was investigated in 0.1 mol/L H2SO4 by voltammetry.MeJA exhibited enhanced oxidation behavior in the presence of sodium dodecyl sulfate(SDS). The electrochemical reaction of MeJA on the electrode was carried out with SDS micelles to improve the solubility of MeJA by hydrophobic interaction.Consequently,the oxidation peak current was sensitively enhanced.The effect of experimental parameters on the oxidative peak current was investigated including the surfactant concentration,supporting electrolyte,accumulation potential and time,and scan rate. In this work, the electrochemical behavior of methyl jasmonate (MeJA) on a glassy carbon electrode was investigated in 0.1 mol/L H2SO4 by voltammetry. MeJA exhibited enhanced oxidation behavior in the presence of sodium dodecyl sulfate (SDS). The electrochemical reaction of MeJA on the electrode was carried out with SDS micelles to improve the solubility of MeJA by hydrophobic interaction. Consequently, the oxidation peak current was sensitively enhanced. The effect of experimental parameters on the oxidative peak current was investigated including the surfactant concentration, supporting electrolyte, accumulation potential and time, and scan rate.
机构地区 College of Pharmacy
出处 《Chinese Science Bulletin》 SCIE EI CAS 2010年第21期2225-2230,共6页
基金 supported by the National Natural Science Foundation of China(90817103 and 20775055) Chen Zilin's start-up fund for the Luojia Chair Professorship of Wuhan University(306276216)
关键词 茉莉酸甲酯 电化学行为 十二烷基硫酸钠 SDS胶束 测定 疏水相互作用 玻碳电极 电化学反应 electrochemical behaviors, glassy carbon electrode (GCE), methyl jasmonate (MeJA), sodium dodecyl sulfate (SDS),voltammetry
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