摘要
本文报道了羧甲基-β-环糊精的一种简便合成方法,并研究了羧甲基-β-环糊精对卤代芳烃类化合物的增溶作用.羧甲基-β-环糊精能与水以任意比例互溶,其水溶液对卤代芳烃有明显的增溶作用.
A simple synthetic method for the synthesis of a cyclodextrin derivative carboxymethyl-β-cy-clodextrin is reported in this paper. Trie application of carboxymethyl-β-cyclodextrin on the solubi-lization of halogenated aromatic hydrocarbons is investigated. Carboxymethyl-β-cyclodextrin can be dissolved in water in unlimited amount. Its water solution can enhance the water solubilities of halogenated aromatic hydrocarbons significantly. The solubilization power of carboxymethyl-β-cyclodex-tnn are depended on the lipophilisity of the halogenated aromatic hydrocarbon and the fitness of the molecular size to the cavity of the cyclodextrin.
出处
《环境化学》
CAS
CSCD
北大核心
1999年第2期131-135,共5页
Environmental Chemistry
基金
国家自然科学基金资助项目 编号:29677065
关键词
羧甲基-β-环糊精
增溶作用
卤代芳烃
carboxymethyl-β-cyclodextrin, solubilization, halogenated aromatic hydrocarbons.