期刊文献+

丙烯醛的极谱法测定 被引量:2

Determination of Acrolein by Polarography
下载PDF
导出
摘要 丙烯醛在酸性介质中可与硫酸联氨发生反应,其产物可在导数示波极谱仪上观察到一波形好、灵敏度高的吸附还原波,峰电位为-0.67v(vs.SCE)。其二阶导数峰高与浓度在1.0×10^(-4)~1.0×10^(-7)mol/L范围内呈良好的线性关系,检测下限为5.0×10^(-8)mol/L。该方法用于测有机合成厂废水中的丙烯醛含量取得满意结果。 Acrolein can react with hydrazine sulfate in the acid medium. Reaction products can reduce at the mercury electrode with a sensitive adsorptive wave [Ep = -0.67v(vs.SCE)]. The concentration of acrolein is linear with peak current in the range of 1.0 × 10-4-1.0×10-7mol/L. The detection limit is 5.0 × 10-8mol/L. This method can be used to determine the concentration of acrolein in wastewater. The behaviour of polarographic wave has been studied and the mechanism of electrode reaction was explored.
机构地区 武汉大学
出处 《上海环境科学》 CAS CSCD 1999年第3期142-143,共2页 Shanghai Environmental Sciences
关键词 丙烯醛 废水 极谱分析 水质监测 Acrolein Wastewater Polarographic analysis
  • 引文网络
  • 相关文献

同被引文献1398

引证文献2

二级引证文献9

;
使用帮助 返回顶部