以(NH_4)_2Ce(NO_3)_6氧化体系合成己二酰-1′,6′-双(4-卤偶氮苯)

Synthesis of Adipic-1',6'-Bis(4-Halogenphenyl Azobenzene) Using (NH_4)_2Ce(NO_3)_6

以自制的己二酰-1′,6′-双(4-卤苯肼)化合物为原料,在室温条件下用(NH4)2Ce(NO3)6氧化体系氧化脱氢得3种己二酰-1′,6′-双(4-卤偶氮苯)化合物。产品的结构经元素分析、IR、1H NMR确证。产率在89%—93%之间。

Adipic-1＇,6＇-bis（4-halogenphenyl hydrazine） compounds have been synthesized at room tempreture with adipic chloride and 4-bromophenyl hydrazine used as starting materials.Adipic-1＇,6＇-bis（4-halogenphenyl azobenzene） were synthesized with oxidation system （NH4）2Ce（NO3）6.The synthesized compounds were confirmed by elemental analysis,IR and 1HNMR,and the yields were 89%—93%.