摘要
Magnetic properties of spin-ladder compounds Sr14（Cu1-yFey）24O41 （0 ≤ y ≤ 0.05） are investigated in the temperature range from 10 to 300 K. The result reveals that all the samples exhibit magnetic crossover behavior in the paramagnetic range, and Fe^3＋ doping can efficiently increase the susceptibility due to the large moment of Fe^3＋. Both the observations are consistent with our previous investigation on transport behaviors, indicating the strong correlation between the magnetism and transport behaviors. The spin gap is evidenced in all the samples, and strengthens as Fe^3＋ doping level increases, which can be associated with the antiferromagnetic interaction between Fe^3＋ and Cu cations.
Magnetic properties of spin-ladder compounds Sr14（Cu1-yFey）24O41 （0 ≤ y ≤ 0.05） are investigated in the temperature range from 10 to 300 K. The result reveals that all the samples exhibit magnetic crossover behavior in the paramagnetic range, and Fe^3＋ doping can efficiently increase the susceptibility due to the large moment of Fe^3＋. Both the observations are consistent with our previous investigation on transport behaviors, indicating the strong correlation between the magnetism and transport behaviors. The spin gap is evidenced in all the samples, and strengthens as Fe^3＋ doping level increases, which can be associated with the antiferromagnetic interaction between Fe^3＋ and Cu cations.
基金
Supported the National Natural Science Foundation of China under Grant No 10974148, the National Science Fund for Talent Training in Basic Science （No J0830310）, and the National Basic Research Program of China under Grant No 2009CB939705, the Fund of Wuhan University （5082003）, and Ministry-of-Education Key Laboratory for the Green Preparation and Application of Functional Materials （Hubei University）.
