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二维氢键层状Mg(Ⅱ)配合物的合成、晶体结构及其抗菌活性(英文)

Synthesis,Crystal Structure and Antibacterial Activity of 2D Hydrogen-bonds Layered Magnesium(Ⅱ) Complex
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摘要 A new complex hexaaquamagnesium(Ⅱ) bis [2-(thiosemicarbazonomethyl)-benzoato],has been prepared and characterized by elemental analysis,IR spectra,molar conductivity and single-crystal X-ray diffraction. The results of crystal structure show that each Mg(Ⅱ) ion is coordinated with six oxygen atoms from water molecules and the complex formed two dimensional layered structure through intramolecule and intermolecule hydrogen bonds. The antibacterial assay of the magnesium(Ⅱ) complex and the ligand were tested using a modified version of the 2-fold serial dilution method,the results show that the complex show considerable antibacterial activity against escherichia coli,bacillus subtilis and staphylococcus white,and the ligand did not show antibacterial activity. A new complex hexaaquamagnesium(Ⅱ) bis [2-(thiosemicarbazonomethyl)-benzoato],has been prepared and characterized by elemental analysis,IR spectra,molar conductivity and single-crystal X-ray diffraction. The results of crystal structure show that each Mg(Ⅱ) ion is coordinated with six oxygen atoms from water molecules and the complex formed two dimensional layered structure through intramolecule and intermolecule hydrogen bonds. The antibacterial assay of the magnesium(Ⅱ) complex and the ligand were tested using a modified version of the 2-fold serial dilution method,the results show that the complex show considerable antibacterial activity against escherichia coli,bacillus subtilis and staphylococcus white,and the ligand did not show antibacterial activity.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2010年第8期1490-1494,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金项目(No.20671073) 山东省自然科学基金项目(No.Y2007B60) 潍坊市科技发展计划项目资助
关键词 2-羧基苯甲醛缩氨基硫脲 Mg(Ⅱ)配合物 合成 晶体结构 抗菌活性 2-(thiosemicarbazonomethyl)-benzoato magnesium complex synthesis crystal structure antibacterial activity
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