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Synthesis,spectroscopic and electrochemical property of an unsymmetrical porphyrin and its Zn compound 被引量:3

Synthesis,spectroscopic and electrochemical property of an unsymmetrical porphyrin and its Zn compound
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摘要 In this article,a new 5-(p-maleicaminophenyl)-10,15,20-triphenylporphyrin(H_2P) and relative zinc compound(ZnP) were synthesized and characterized by means of elemental analyses,UV-vis,IR,MS and 1H NMR spectroscopies.Furthermore,we have investigated the fluorescence spectroscopy of these compounds.The oxidation and reduction properties of the compounds were studied by the cyclic voltarnmetry,the oxidation-reduction potentials were obtained. In this article,a new 5-(p-maleicaminophenyl)-10,15,20-triphenylporphyrin(H_2P) and relative zinc compound(ZnP) were synthesized and characterized by means of elemental analyses,UV-vis,IR,MS and 1H NMR spectroscopies.Furthermore,we have investigated the fluorescence spectroscopy of these compounds.The oxidation and reduction properties of the compounds were studied by the cyclic voltarnmetry,the oxidation-reduction potentials were obtained.
机构地区 College of Chemistry
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第7期769-773,共5页 中国化学快报(英文版)
基金 supported by the National Science Foundation of China(No.20801022).
关键词 SYNTHESIS PORPHYRIN Cyclic voltammetry FLUORESCENCE Synthesis Porphyrin Cyclic voltammetry Fluorescence
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