摘要
在水溶液中，用NaBrO3和HBr与强碱离子交换树脂反应，制备了具有良好稳定性的载溴树脂，该树脂于室温下，在CH3OH和CH2Cl2溶液中，在CaCO3存在下，有效地溴化芳胺为溴代芳胺化合物，得到较好的产率，同时探讨了甲醇在反应中的作用．
The bromine - supported resin was prepared by sodium bromate and hydrobromic acid reacting with strong basic resin in water. The aromatic amines were bromized to give bromo- substituted aromatic amines using the bromine - supported resin in dichloromethane - methanol containing calcium carhonate powder at room tempture, and it gave a good yields. The effect of methanol in the reaction was also discussed.
出处
《湖北大学学报（自然科学版）》
CAS
1999年第1期64-66,共3页
Journal of Hubei University：Natural Science
关键词
载溴树脂
溴化
芳胺
离子交换树脂
Bromine-supported resin
Bromination
Aromatic amines
