CH_3OOCCH_2CH_2SnCl(2-OC_6H_4CH=NC_6H_4O-2)·C_6H_6的晶体结构

THE CRYSTAL STRUCTURE FOR CH3OOCCH2CH2SnCl(2OC6H4CH=NC6H4O2)·C6H6

利用３－三氯锡基丙酸甲酯与Ｎ－（２－羟基苯基）水杨醛亚胺（Ｌ）在苯中反应合成了标题化合物．该化合物的晶体结构分析表明，该晶体属三斜晶系，空间群Ｐ１，ａ＝８．６４８（２），ｂ＝９．３３２（２），ｃ＝１４．４１７（４），α＝９７．４２（３），β＝１０２．９６（３），γ＝９７．６８（３）°．化合物具有分子内羰基氧原子和Ｌ的氧、氮。

The title compound was synthesized by the rea ction of methyl 3trichlorostannylpropionate with N(2hydroxyphenyl)salicy laldimine (L) in benzene.The crystal structure was dermined by the Xray diffra ction analysis.The crystal belongs to triclinic system,space group p1 w ith a=8.648(2),b=9.332(2),c=14.417(4),α=97.42(3),β=102.96(3),γ=97.68(3)°.T he tin atom adopts a distorted octahedral geometry via the O,N,O atoms of the ch elating ligand L and irtramolecular carbonyl oxygen atom to tin coordination.