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5-三甲基硅烷基-2-呋喃甲醛的脱硅烷基酰化反应

Acyldesilylation of 5-trimethylsilyl-2-furancarboxaldehyde
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摘要 报道了5-三甲基硅烷基-2-呋喃甲醛与几种不同酰氯之间的脱硅烷基酰化反应,制得5-二氯甲基-2-酰基呋喃及5-酰基-2-呋喃甲醛,同时探讨了不同酰氯对反应活性的影响. Acyldesilylation of 5-trimethylsilyl-2-furancarboxaldehyde with several kinds of acyl chlorides was investigated and 2-acyl-5-dichloromethylfuran ware obtained as main products.5-acyl-2-furancarboxaldehydes were found after hydrolyzing of the corresponding dichloro compounds.The reaction activities of Acyldesilylation for different acyl chlorides were also discussed.
出处 《延边大学学报(自然科学版)》 CAS 1999年第1期40-42,共3页 Journal of Yanbian University(Natural Science Edition)
关键词 呋喃甲醛 酰基呋喃 脱硅烷基酰化 三甲基硅烷基 Acyl-5-dichloromethylfuran 5-Acyl-2-furancarboxaldehyde Acyldesilylation
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