铜体系催化原子转移自由基聚合机理研究的讨论

The Discussion of the Mechanism for the Atom Transfer Radical Polymerization (ATRP) Catalyzed by Copper (Cu) Complex *

在综述现有文献的基础上，结合作者的研究结果，对ＡＴＲＰ的反应机理进行了讨论。同时，作者提出了ＡＴＲＰ中具有催化活性的络合物结构及自由基增长反应的可能历程。

The mechanism of the Atom Transfer Radical Polymerization (ATRP) is discussed base on the review of the literature up to data as well as the authors' research results.Consequentially,the structure of the catalyst center and the mode of propagation are postulated.