摘要
以二茂铁为起始原料,经多步反应,合成了1,1’-二茂铁二乙酸酐,后者与取代苯胺反应,合成了十四种新型二茂铁二乙酸单酰胺,并由元素分析、红外光谱和核磁共振氢谱鉴定了化合物的结构。此外,对二茂铁二羧酸单酰胺与过渡金属的螯合反应进行了初步研究。
14 N-aryl-(1'-carboxymethylferrocenyl)-acetamides have been synthesized by reaction of 1,1 '-ferrocenediacetic acid anhydride with aromatic amines. The reactivities of the aromatic amines in the reaction have been studied. And the structures of the products were characterized by elementary analysis, IR and 1H NMR. The reaction of N-2-hydroxy(phenyl)-(1'-carboxymethylferrocenyl)-acetamide with
2Cucl2.H2O was also tentatively studied. The composition of the corresponding cupper complex
2H2O) was confirmed by elementary analysis.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1999年第2期176-180,共5页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金
关键词
二茂铁
二茂铁二羧酸
单酰胺
螯合反应
1, 1'-ferrocenediacetic acid anhydride, N-aryl-( 1'-carboxymethylferrocenyl )-acetamide, chelate reaction