(四氮杂十四元大环)·双(O,O′-二(1-萘基)二硫代磷酸根)合镍或铜的合成与谱学性质

SYNTHESIS AND SPECTROSCOPIC PROPERTIES OF (TETRAAZACYCLOTETRADECA)·BIS(O,O′ BI(1 NAPHTHYL)DITHIOPHOSPHATE)NICKEL OR COPPER COMPLEXES

Ｏ，Ｏ′－二烃基二硫代磷酸的铵盐和配合物可作为润滑油和燃油的添加剂、高分子材料的稳定剂以及人造橡胶的硫化促进剂。［（ＲＯ）２ＰＳＳ］ｎＭ作为润滑油抗氧化剂时，常需要加入一些简单胺，这样可有效地缩减氧化作用［１，２］。为此人们合成了一些含简单氮配体的过...

Four new nickel and copper complexes [ML{SSP(OC 10 H 7 1) 2} 2], where M=Ni(Ⅱ), Cu(Ⅱ); L=5,7,7,12,14,14 hexamethyl 1,4,8,11 tetraazacyclotetradeca 4,11 diene(hmtade) or 5,7,7,12,14,14 hexamethyl 1,4,8,11 tetraazacyclotetradecane(hmta); SSP(OC 10 H 7 1) 2=O,O′ bis(1 naphthy)dithiophosphate, were synthesized and characterized by elemental analysis, molar conductivity, infrared spectra, electronic spectra and TG DTA thermal analysis. The complexes are non electrolytes in DMSO. O,O′ bis(1 naphthyl) dithiophosphate ligand that behaves in monodentate fashion coordinates to metal ion.