摘要
A new chiral mono-complex(S)-[Zn(FcCH2NHCH(CH2CH(CH3)2)COO)2·H2O]·3H2O has been synthesized by the reaction of(S)-FcCH2NHCH(CH2CH(CH3)2)COONa and ZnAc2.X-ray diffraction technique reveals that the central Zn2+ ion coordinates with two(S)-FcCH2NHCH(CH2CH(CH3)2)COO-and one water molecule.The crystal belongs triclinic with space group P1.The cell parameters are:a=11.1883(4) ;b=11.1934(4) ;c=30.6717(15) ;α=97.6160(10)°,β=97.6120(10)°,γ=90.157(11)°.The electrochemical properties and fluorescence properties of the title complex and the pure ligand are determined.
A new chiral mono-complex（S）-[Zn（FcCH2NHCH（CH2CH（CH3）2）COO）2·H2O]·3H2O has been synthesized by the reaction of（S）-FcCH2NHCH（CH2CH（CH3）2）COONa and ZnAc2.X-ray diffraction technique reveals that the central Zn^2＋ ion coordinates with two（S）-FcCH2NHCH（CH2CH（CH3）2）COO-and one water molecule.The crystal belongs triclinic with space group P1.The cell parameters are：a=11.1883（4） ;b=11.1934（4） ;c=30.6717（15） ;α=97.6160（10）°,β=97.6120（10）°,γ=90.157（11）°.The electrochemical properties and fluorescence properties of the title complex and the pure ligand are determined.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2010年第8期995-998,共4页
Chemical Research and Application
基金
国家自然科学基金(J0830412)项目资助
河南省教育厅自然科学研究计划项目(2010A150025)资助
关键词
配合物
二茂铁甲基亮氨酸钠
晶体结构
电化学性质
荧光性质
coordintion complex
ferrocenoyl amino
crystal structure electrochemical character
fluorescence property
