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2-[(9-苯基)-9H-3-咔唑基]-5-[(9-对甲苯基)-9H-3-咔唑基]吡啶的合成及其光谱性能 被引量：3

Synthesis and Spectral Properties of 2-(9-Phenyl-9H-carbazol-3-yl)-5-(9-p-tolyl-9H-carbazol-3-yl)pyridine
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摘要 以咔唑和2,5-二溴吡啶为初始原料,经Ullmann反应、NBS亲电取代反应和Suzuki偶联等反应,合成了一种新型的磷光配体2-[(9-苯基)-9H-3-咔唑基]-5-[(9-对甲苯基)-9H-3-咔唑基]吡啶(5),其结构经1HNMR,ESI-MS及元素分析表征。研究了5在二氯甲烷中的荧光光谱和紫外吸收光谱。 A novel phosphorescent ligand,2-（9-phenyl-9H-carbazol-3-yl）-5-（9-p-tolyl-9H-carbazol-3-yl）pyridine（5）,was synthesized by Ullmann reaction,NBS electrophilic substitution and Suzuki coupling reaction from carbazole and 2,5-dibromopyridine.The structure was characterized by 1H NMR,ESI-MS and elemental analysis.The UV-Vis and fluorescence spectra of 5 in dichloromethane solution were investigated.
作者 范和良 戴延凤 刘望博 胥诗华 黄海方 高希存
机构地区 南昌大学化学系
出处 《合成化学》 CAS CSCD 北大核心 2010年第4期420-423,428,共5页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(60868001) 教育部留学基金资助项目(Z202873)
关键词 咔唑 SUZUKI偶联 NBS亲电取代 合成 光谱性能 carbazole Suzuki coupling NBS electrophilic substitution synthesis spectral property
分类号 O626.32 [理学—有机化学]
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  • 1Baldo M A,O'Brien D F,You Y,et al Highly efficient phosphorescent emission from organic electroluminescent devices[J].Nature,1998,395:151-154.
  • 2Welter S,Brunner K,Hofstraat J W,et al.Electroluminescent device with reversible switching between red and green emission[J].Nature,2003,421:54-57.
  • 3Veinot J G C,Marks T J.Toward the ideal organic light-emitting diode.The versatility and utility of interfacial tailoring by cross-linked siloxaneInterlayers[J].Acc Chem Res,2005,38:632-643.
  • 4Holder E,Langeveld B M W,Schubert U S.New trends in the use of transition metal-ligand complexes for applications in electroluminescent devices[J].Adv Mater,2005,17:1109-1121.
  • 5Md K Nazeeruddin,Humphry-Baker R,Berner D,et al.Highly phosphorescence iridium complexes and their application in organic light-emitting devices[J].J Am Chem Soc,2003,125:8790-8797.
  • 6Michael S Lowry,William R Hudson,Robert A Pascal,et al.Accelerated luminophore discovery through combinatorial synthesis[J].J Am Chem Soc,2004,126:14129-14135.
  • 7Michael S Lowry,Jonas I Goldsmith,et al.Single-layer electroluminescent devices and photoinduced hydrogen production from an ionic iridium(Ⅲ) complex[J].Chem Mater,2005,17:5712-5719.
  • 8Kyu Reon Lee,Nam Hwi Hur,Min-Sik Eum,et al.New heteroleptic iridium complexes having one biphenyl-2,2-diyl and two bipyridyl based ligands[J].Dalton Trans,2009,19:3650-3652.
  • 9Shih-Chun Lo,Ruth E Harding,Paul L Burn,et al.High-triplet-energy dendrons:Enhancing the luminescence of deep blue phosphorescent Iridium(Ⅲ) complexes[J].J Am Chem Soc,2009,131:16681-16688.
  • 10Jun Hong Yao,Changgua Zhen,Kian Ping Loh,et al.Novel iridium complexes as high-efficiency yellow and red phosphorescent light emitters for organic light-emitting diodes[J].Tetrahedron,2008,64(48):10814-10820.

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合成化学
2010年 第4期

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