苯乙酮双缩二氨基硫脲合Sn(Ⅱ)、Pb(Ⅱ)配合物的直接电化学合成

THE DIRECT ELECTROCHEMICALSYNTHSIS OF Sn(), Pb() COMPLEX OF 1,5-BIS(ACETOPHENONE) THIOCARBOHYDRAZON

合成了新的含硫希夫碱配体苯乙酮双缩硫代对称二氨基脲，在以此化合物为配体的非水溶剂中，用Ｓｎ、Ｐｂ金属做阳极，首次用电化学金属阳极氧化法合成了苯乙酮双缩硫代对称二氨基脲（ＨＬ）与Ｓｎ（Ⅱ）、Ｐｂ（Ⅱ）的金属配合物，通过元素分析、红外光谱、紫外光谱、磁化率、摩尔电导等对配体和配合物进行了表征．

The new schiff base containing sulfur 1,5-bis(acetophenone) thiocarbohydrazone(HL) was synthesized.And in the ligand(HL) nonaqueous solvent,the Sn() and Pb() metal complexes of 1,5bis(acetophenone) thiocarbohydrazon were synthesized by the electrochemical oxidation with Sn and Pb as anodics.The ligand and complexes were characterized by elemental analysis,IR,UV,magnetic measurement and molar conductivity etc.