C_(60)/聚苯胺自组装薄膜的制备及性能研究

A study on preparation of C_(60)/polyaniline self-assembly monolayer and its properties

依靠化学键组装法在导电玻璃ITO表面制备了C60/聚苯胺薄膜。通过紫外-可见光谱证实了导电聚苯胺和足球烯之间存在着π-π相互作用。在C60亲电子作用的影响下,导电聚苯胺薄膜的电化学氧化还原性质发生了显著变化,表明聚苯胺和C60之间发生了电荷转移。

The C60/polyaniline（PANI） thin film is prepared on the ITO surface by chemical linkage. It is found that there are π-π interactions between C60 and PANI examined by UV-Vis spectra, and the electrochemical redox behaviors of the conducting polyaniline layer are greatly changed induced by electron accepting from C60, which shows there are electronic interactions between C60 and PANI.