期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

镁铝氧化物催化生物质衍生物的羟醛缩合研究 被引量：1

Study on aldol-condensation of biomass-derived carbohydrates catalyzed by Mg-Al-oxide
下载PDF
导出
摘要 研究了在水相中加工生物质衍生物制备液体燃料的新方法。制备镁铝氧化物固体催化剂,在40℃下,考察糠醛和丙酮在催化作用下的羟醛缩合反应的动力学;以稀硫酸为催化剂制备纤维素的水解液,在40℃下,研究镁铝氧化物催化剂对纤维素水解液羟醛缩合反应的催化作用,得到了纤维素水解液羟醛缩合反应后的不溶于水的油性产物。 A new method that converts biomass-derived carbohydrates into liquid fuels in water phase was researched.The Mg-Al oxide solid catalyst was prepared.Reaction kinetics of aldolcondensation of furfural and acetone catalyzed by Mg-Al oxide at 40 ℃ was studied.The hydrolysis solution of cellulose was prepared.Aldol-condensation of hydrolysis solution of cellulose by Mg-Al oxide catalyst at 40 ℃ was studied,and water-insoluble oil-products was isolated from the reaction system.
作者 孙培勤 邢士玉 孙绍晖 陈俊武
机构地区 郑州大学化工与能源学院
出处 《可再生能源》 CAS 北大核心 2010年第4期62-65,68,共5页 Renewable Energy Resources
关键词 生物质 糠醛 羟醛缩合 镁铝氧化物 biomass furfural aldol condensation Mg-Al-oxide
分类号 TK6 [动力工程及工程热物理—生物能] S216.2 [农业科学—农业机械化工程]
  • 相关文献

参考文献10

  • 1HUBER G W,CHHEDA J N,BARRETT C J,et al.Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates[J].Science,2005,308:1446-1450.
  • 2HUBER G W.Breaking the chemical and engineering barriers to lignocellulosic biofuels:next generation hydrocarhon biorefineries[M].Washington:Washington D.C.2008.
  • 3BARRETT C J,CHHEDA J N,HUBER G W,et al.Single-reactor process for sequential aldol-condensation and hydrogenation of biomass-derived compounds in water[J].Applied CatalysisB:Environmental,2006,66(1-2):111-118.
  • 4CHHEDA J N,DUMESIC J A.An overview of dehydration,aldol-condensation and hydrogenation processes for production of liquid alkanes from biomass-derived carbohydrates[J].Catalysis Today,2007,173(1-4):59-70.
  • 5WEST R M,LIU Z Y,PETER M,et al.Carbon-carbon bond formation for biomass-derived furfurals and ketones by aldol condensation in a biphasic system[J].Journal of Molecular Catalysis A:Chemical,2008,296(1-2):18-27.
  • 6RAO K K,GRAVELLE M,VALENTE J S,et al.Activation of Mg-Al hydrotalcite catalysts for aldol condensation reactions[J].Journal of Catalysis,1998,173(1):115-121.
  • 7CLIMENT M J,CORMA A,IBORRA S,et al.Increasing the basicity and catalytic activity of hydrotaicites by different synthesis procedures[J].Journal of Catalysis,2004,225(2):316-326.
  • 8谭露璐,钱君律,伍艳辉.羟醛缩合催化剂研究进展[J].化学工业与工程,2006,23(1):70-74. 被引量：41
  • 9ROCHA S M,MANUEL A,COIMBRA I D.Occurrence of furfuraldehydes during the processing of Quercus suher L.cork.Simultaneous determination of furfural,5-hydroxymethylfurfural and 5-methylfurfural and their relation with cork polysaccharides[J].Carbohydrate Polymers,2004,56(3):87-289.
  • 10庄新姝,王树荣,骆仲泱,安宏,岑可法.纤维素低浓度酸水解试验及产物分析研究[J].太阳能学报,2006,27(5):519-524. 被引量：34

二级参考文献29

  • 1SUSUMU SAITO, MASAHITO SHIOZAWA, HISASHI YAMAMOTO. Mixed crossed aldol condensation between conjugated esters and aldehydes using aluminum tris (2,6-diphenylphenoxide)[ J ] . Angewandte Chemie International Edition, 1999,38(12): 1769 - 1771.
  • 2SUSUMU SAITO, HISASHI YAMAMOTO. Directed aldol condensation [ J ] . Chemistry-A European Journal, 1999, 5(7):1959-1962.
  • 3TANNER R, GILL P, WEI.LS R, et al. Aldol condensation reactions of acetone and formaldehyde over vanadium phosphate catalysts: Comments on the acid-base properties[J]. Chem Phys,2002,4:688 - 695.
  • 4PAULIS M, MARTIN M,SORIA D B, et al. Preparation and characterization of nibium oxide for the catalytic aldol condensation of acetone [ J ]. Applied Catalysis A:General, 1999,180(1 - 2):411 - 420.
  • 5DUMITRIU E, HULEA V, FECHETE I, et al. The aldol condensation of lower aldehydes over MFI eolites with different acidic properties[J]. Microporous and Mesoporous Materials,2001,43:341-359.
  • 6LEOPEZ J, VALENTE J S, CLACENS J M, et al. Hydrogen transfer reduction of 4-tert-butylcyclohexanone and aldol condensation of benzaldehyde with acetophenone on basicsolids [ J ]. Journal of Catalysis, 2002,208(1): 30 - 37.
  • 7WINTER, GEORGE, ROBERT. Process for the production of 3-hydroxypropanal [ P ] . WO: 0206393,2002-01-24.
  • 8AI M. Formation of acrylaldehyde by vapor-phase aldol condensation Ⅱ phosphate catalysts [ J ]. Bull Chem Soc Jpn,1991,64:1346-1350.
  • 9AI M.Vapor-phase aldol condensation of formaldehyde with acetic acid on V205-P205 catalysts [ J ]. Journal of Catalysis, 1987,107:201-208.
  • 10AI M. Formation of acrylaldehyde by vapor-phase aldol condensation Ⅰ basic oxide catalysts [J]. Bull Chem Soc Jpn, 1991,64: 1342 - 1345.

共引文献73

同被引文献5

引证文献1

二级引证文献2

可再生能源
2010年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部