摘要
The title compound formulated as Cu2（C13H11N6OF2）（N3）3CH3OH was synthesized and structurally characterized by elemental analysis,IR and single-crystal X-ray diffraction.In the structure of the complex,the deprotonated fluconazole and azide anion link two copper centers to construct a binuclear SBU and the azide anion exhibits a μ1,1-coordination mode.Each triazole group of fluconazole links two SBUs and the compound exhibits a chain-like architecture with strong antiferromagnetism.
The title compound formulated as Cu2（C13H11N6OF2）（N3）3CH3OH was synthesized and structurally characterized by elemental analysis,IR and single-crystal X-ray diffraction.In the structure of the complex,the deprotonated fluconazole and azide anion link two copper centers to construct a binuclear SBU and the azide anion exhibits a μ1,1-coordination mode.Each triazole group of fluconazole links two SBUs and the compound exhibits a chain-like architecture with strong antiferromagnetism.
基金
Supported by the Chongqing University Postgraduate Science (No.200911A1B0010317)
Innovation Fund and Innovative Talent Training Projects of the Third Stage of "211 Project"of Chongqing University(No.S-09103)
the Natural Science Young Scholars Foundation of Chongqing University,Large-scale Instrument and Equipment Open Foundation of Chongqing University
Scientific Research Start-up Foundation of Chongqing University
