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Concentration and separation of vanadium from alkaline media by strong alkaline anion-exchange resin 717 被引量:1

Concentration and separation of vanadium from alkaline media by strong alkaline anion-exchange resin 717
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摘要 With strong alkaline anion-exchange resin 717 as the sorbent and NaOH solution as the eluent, a study on the sorption from alkaline solution and elution of vanadium(V), silicon(iv), and aluminium(III) was carried out. Different parameters affecting the sorption and elution process, including temperature, pH values as well as the ratio of resin to solution, were investigated. The results show that sorption degree of vanadium(V) increases with a decrease ofpH values, and V(V) ions are easier sorbed than Si(IV) and AI(III) ions under the same conditions. The sorption degree ofV(V), Si(IV), and AI(III) at pH 9.14 for 15 man are 90.6%, 33.5%, and 21.6%, respectively. Si(IV), AI(III), and V(V) ions sorbed on 717 resin were eluted by use of 2 mol·L^-1 NaOH solution; the desorption degree ofV(V), Si(IV), and AI(III) for 5 min are 81.7 %, 99.1%, and 99.3%, respectively. With strong alkaline anion-exchange resin 717 as the sorbent and NaOH solution as the eluent, a study on the sorption from alkaline solution and elution of vanadium(V), silicon(iv), and aluminium(III) was carried out. Different parameters affecting the sorption and elution process, including temperature, pH values as well as the ratio of resin to solution, were investigated. The results show that sorption degree of vanadium(V) increases with a decrease ofpH values, and V(V) ions are easier sorbed than Si(IV) and AI(III) ions under the same conditions. The sorption degree ofV(V), Si(IV), and AI(III) at pH 9.14 for 15 man are 90.6%, 33.5%, and 21.6%, respectively. Si(IV), AI(III), and V(V) ions sorbed on 717 resin were eluted by use of 2 mol·L^-1 NaOH solution; the desorption degree ofV(V), Si(IV), and AI(III) for 5 min are 81.7 %, 99.1%, and 99.3%, respectively.
出处 《Rare Metals》 SCIE EI CAS CSCD 2010年第5期439-443,共5页 稀有金属(英文版)
基金 supported by the Guangxi Natural Scientific Foundation of China(No.0832111) the Guangxi Large Apparatus Cooperation Community Net Foundation of China(No.695-2008-108)
关键词 HYDROMETALLURGY ion exchange VANADIUM alkaline solution SORPTION hydrometallurgy ion exchange vanadium alkaline solution sorption
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