期刊文献+

化学氧化聚合法合成高电导率聚苯胺研究进展 被引量:5

Research progress of chemical oxidative polymerization of polyaniline with high electrical conductivity
下载PDF
导出
摘要 化学氧化聚合法是制备聚苯胺的最常用方法。本文综述了该法合成聚苯胺的机理及聚合条件对产物电导率的影响,指出了目前应用化学氧化聚合法制备聚苯胺存在的问题及今后的研究方向。 Chemical oxidative polymerization is one of the most usually used methods for the preparation of PANI.The polymerization mechanism of aniline was summarized systematically and the influence of polymerization conditions on electrical conductivity of as polymerized PANI was reviewed.Finally,personal viewpoints were given on the unresolved problems in chemical oxidative polymerization of PANI and on the research directions.
出处 《化工新型材料》 CAS CSCD 北大核心 2010年第8期27-29,127,共4页 New Chemical Materials
关键词 聚苯胺 电导率 化学氧化聚合 分子结构 polyaniline electrical conductivity chemical oxidative polymerization molecular structure
  • 相关文献

参考文献32

  • 1张东华,王杨勇,井新利,石玉.聚苯胺的酶促合成[J].高分子材料科学与工程,2004,20(6):11-14. 被引量:6
  • 2Stejskal J,Gilbert R G.Polyaniline.preparation of a conducting polymer[J].Pure Appl Chem,2002,74(5):857-867.
  • 3MacDiarmid A G,Chiang J C,Halpern M,et al.Polyaniline:interconversion of metallic and insulating forms[J].Mol Cryst Liq Cryst,1985,121 (1-4):173-180.
  • 4Armes S P,Miller J P.Optimum reaction conditions for the polymerization of aniline in aqueous solution by ammonium persulphate[J].Synth Met,1988,22(4):385-393.
  • 5Rao P S,Subrahmanya S,Sathyanarayana D N.Water-soluble conductive blends of polyaniline and poly(vinyl alcohol) synthesized by two emulsion pathways[J].J Appl Polym Sci,2005,98(2):583-590.
  • 6Shreepathi S,Holze R.Spectroelectrochemical investigations of soluble polyaniline synthesized via new inverse emulsion pathway[J].Chem Mater,2005,17(16):4078-4085.
  • 7Rao P S,Sathyanarayana D N,Palaniappan S.Polymerization of aniline in an organic peroxide system by the inverted emulsion process[J].Macromolecules,2002,35(13):4988-4996.
  • 8Liu W,Kumar J,Tripathy S.Enzymatic synthesis of conducting polyaniline in micelle solutions[J].Langmuir,2002,18(25):9696-9704.
  • 9Dias H V,Rajapakse R M,Krishantha D M,et al.Eco-friendly synthesis of high-quality polyaniline using a copper(II) scorpionate catalyst[J].J Mater Chem,2007,17(18):1762-1768.
  • 10Black N,Karagoz B.Polymerization of aniline by copper-catalyzed air oxidation[J].J Polym Sci A:Polym Chem,2006,44(20):6025-6031.

二级参考文献29

共引文献52

同被引文献46

引证文献5

二级引证文献23

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部