芳环和芳杂环三硝基乙基羧酸酯的合成研究

STUDIES ON SYNTHESIS OF ARYL AND HETEROCYCLIC TRINITRO-ETHYL CATBOXYLIC ESTERS

本文简述了均(三硝基乙基)苯三甲酸酯、双(三硝基乙基)间苯二甲酸酯、5-硝基-双(三硝基乙基)间苯二甲酸酯、α-三硝基乙基噻吩甲酸酯、5-硝基-2-三硝基乙基呋喃甲酸酯、2.6-二(三硝基乙基)吡啶甲酸酯、α-偕二硝基丙基噻吩甲酸酯等7个新化合物的合成;改进了合成方法中运用的有关反应的一些条件,测定了安定性、感度等性质。

The contents of this paper are ths synthesis of the compounds: s-trini-tro-etbyl-tris-bsnzoate , m-bis ( trinitro-ethyl ) dibenzoate , 5-nitro-m-bis (trinitro-etbyl) dibenzoate,α-trinitro-ethyl-thiophene carboxylate, 5-nitro-2 - trinitro-ethyl-furan carboxylate , 2.6-bis ( trinitro-ethyl ) pyridine carboxylate,α-2.2-dinitro-propyl-thiopbene carboxylate. Besides the synthesis of these seven new compounds, some novel simplified operations and the experiments for the thermal and shock stabilities are given.For the other two new compounds, trinitro-ethyl-furan carboxylate, 2.2-dinitro-propyl furan carboxylate see separatly in other papers to be published.