期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

三苯基膦-水体系还原芳基磺酰氯制备芳基硫酚

Preparation of Arylthiols by Reduction of Aryl Sulfonyl Chlorides with Triphenylphosphine-H_2O System
下载PDF
导出
摘要 以甲苯为溶剂,室温条件下,PPh3-H2O体系能够高效并且具有化学选择性地还原各种芳基磺酰氯,生成相应的芳基硫酚。提供了一种反应时间短,以高转化率、高收率制备芳基硫酚的新方法。产物结构经核磁共振光谱、质谱得到了证实。 Several arylthiols were prepared by reduction with triphenylphosphine-H2O system efficiently and chemoselectively at room temperature in toluene solvent.A new method of preparing arylthiols has been supplied,the method has high yield and conversion,short reaction time.The structures of products were confirmed by 1H NMR and MS spectra.
作者 滕文彬 杜桂强
机构地区 东营市海科新源化工有限责任公司
出处 《当代化工》 CAS 2010年第4期372-374,共3页 Contemporary Chemical Industry
关键词 芳基磺酰氯 芳基硫酚 三苯基膦 还原 Arylthiol Aryl sulfonyl chloride Triphenylphosphine Reduction
分类号 TQ247.1 [化学工程—有机化工]
  • 相关文献

参考文献13

  • 1章思规 章伟.精细化学品及中间体手册[M].北京:化学工业出版社,2004.1079,1082.
  • 2William S Hurt. O, S-dialkyl o-phenylthio-phenyl phosphorothiol ates/phosphoroditlaioates and their derivatives and pesticidal use: US,4029774[P]. 1975-05-12.
  • 3Newman M S, Karnes H A. The conversion of phenols to thiophenols via dialkylthiocarbamates [J]. J Org Chem, 1966,31 (12) :3980-3984.
  • 4Kwart H, Evans E R. The vapor phase rearrangement of thioncarbo nares and thioncarbamates[J]. J Org Chem, 1966,31(2) :410-413.
  • 5Jeremy N Harvey,Jesffls Jover,Guy C Lloyd-Jones,et al. The Newman Kwart rearrangement of o-aryl thiocarbamates: substantial reduction in reaction temperatures through palladium catalysis[J]. Angew Chem lnt Ed, 2009,48: 7612-7615.
  • 6Al-Kazimi H R,Tarbell D S,Plant D. A study of the Sch?nberg rearrangement of diaryl thioncarbonates to diaryl thiolcarbonates [J]. J Am Chem Soc, 1955,77(9) : 2479-2482.
  • 7Donald H Powers, Stanley Tarbell D.The Schonberg rearrangement. Kinetics of the rearrangement of his- ( 4-chlorophenyl )thiocarbonate to the thiolcarbonate[J]. J Am Chem Soc, 1956,78( 1 ) :70-71.
  • 8Campaigne E, Osbom S W. Improved procedure for preparation of aromatic thiols[J]. J Org Chem, 1957,22(5 ) : 561-562.
  • 9Lamar Field,Frederick A Grunwald. Lithium aluminum hydride reduction of certain sulfonic acid derivatives[J]. J Org Chem, 1951, 16(6) : 946-953.
  • 10杜晓华,许响生,许丹倩,徐振元.中间体5-氨基-2-氯-4-氟苯硫酚合成方法的改进[J].农药,2003,42(9):19-20. 被引量：2

二级参考文献9

  • 1Barry M Trost, Robert A Kunz. New synthetic reactions A convenient approach to methyl-3-Oxo-4-Pentenoate[J]. J Org Chem, 1974, 39(17) :2648 - 2650.
  • 2杨如义 郑能武 许海涛.配位聚合物[Nd2（CsH5N04）3·4H20]∞的单晶结构[J].科学通报,2000,47(20):1456-1459.
  • 3Lisitsyn V N, Kukalenlo L S, Tsatsakis A M. Synthesis and some reaction of 2, 7-and 2, 6-naphthlene biscthioacetic acids[J]. Zh Org Khim, 1985, 21 ( 1 ) : 161 -164.
  • 4Rule Mark, Tanner James Thomas Ⅲ . Process for preparation of aromatic thiols[P]. USA, 9323369. 1993-11-25.
  • 5Rule Mark, Tanner James Thomas Ⅲ . Process for preparation of aromatic thiols from aromatic halides and thiourea[P]. USA, 5338866. 1994-08-16.
  • 6Stepanov B I, Rodionov V Ya, Andreeva M A, et al.Synthesis of 1, 5-disubstituted sulfur-containing naphene derirative [ J ]. Izv Vyssh Ueheb Zaved Khim Khim Tekhnol, 1974, 17(5) 1773 - 774.
  • 7阎圣刚,王之键,贾卫民.1,5-萘二硫醇的合成[J].化学试剂,2000,22(4):239-239. 被引量：2
  • 8杜晓华,顾建波,徐振元.中间体5-氨基-2-氯-4-氟苯硫基乙酸甲酯的制备[J].农药,2003,42(1):14-15. 被引量：1
  • 9芳香双硫酚合成方法[J].科技开发动态,2003(2):40-40. 被引量：1

共引文献43

当代化工
2010年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部