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Ortho-hydroxy assisted and copper-catalyzed oxidation of benzylic alcohol 被引量:1

Ortho-hydroxy assisted and copper-catalyzed oxidation of benzylic alcohol
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摘要 An efficient and simple protocol for the synthesis of o-hydroxyarylketones has been developed. The reaction proceeds smoothly with catalytic amounts of copper catalyst under air atmosphere without ligands. This study indicates that the o-hydroxy plays an important role in the oxidation of alcohol to the corresponding carbonyl compounds. An efficient and simple protocol for the synthesis of o-hydroxyarylketones has been developed. The reaction proceeds smoothly with catalytic amounts of copper catalyst under air atmosphere without ligands. This study indicates that the o-hydroxy plays an important role in the oxidation of alcohol to the corresponding carbonyl compounds.
出处 《Chinese Science Bulletin》 SCIE EI CAS 2010年第25期2817-2819,共3页
基金 supported by the National Natural Science Foundation of China (20628202 and 90813008)
关键词 催化氧化 铜催化剂 邻羟基 苄醇 羰基化合物 空气气氛 配体 o-hydroxy, oxidation, o-hydroxyarylketones, copper catalysis
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