基于4-吡啶氰原位合成的四氮唑铜配合物研究

Study on 4-Cyanopyridine Complex to A New Coordination of Tetrazolium

本文以4-吡啶氰和一价铜盐,在溶剂热条件下原位自组装合成了一个新的配合物.通过X射线单晶衍射测定了其结构,该配合物属于单斜晶系,空间群为P2(1)/c,a=5.7(nm),b=15.9(nm),c=10.8(nm),a=90°,β=93.8,V=984.2nm3,配体为刚性配位,形成一个三维的具有孔道的结构,还测定了该配合物的荧光性质。

One new coordination complex is synthesized through self-assembly solventhermal in Situ from reaction of CuSCN with 4- Cyanopyridine . Crystal structural analyses reveal that it belongs to space group Monoclinic with a=5.7（nm）,b=15.P（nm）,c=10.8（nm）,a=90°,β=93.8,V= 984.2nm^3.Each Cu（ I ） ion is linked by one N of four ligands, it is of 3D hole structure, furthermore, solid-state photoluminescence properties are also reported.