S-甲基二硫代肼基甲酸的西夫碱双铜配合物的合成及其在双层脂膜上的电子传递

SYNTHESIS OF BI-COPPER (Ⅱ) S-METHYL DITHIOCARBAZATE SCHIFF BASE COMPLEX AND ITS ELECTRON TRANSFER ACROSS BLM

合成了S-甲基二硫代肼基甲酸的西夫碱双铜配合物并用各种物理方法对其进行了结构鉴定。生物试验表明配合物对各类微生物具有一定抑制作用。用循环伏安法研究了经双铜配合物修饰的双层脂膜(bilayer lipid membrane,BLM)上的氧化还原反应,表明配合物在膜内起电子递体的作用。

A bicopper (Ⅱ) complex Cu_2L_2Cl_2 with S-methyldithiocarbazate ligand was synthesized and characterized by various physical methods. It has been found that the complex has an activity of inhibition against some moulds bacteria and yeasts. Redox reactions on bilayer lipid membrane (BLM) modified by Cu_2L_2Cl_2 was investigated by cyclic voltammetry method and the action of electron carrier of this complex on BLM was reported.