摘要
以MNT(n-Bu)2为前体,采用模板法合成了八正丁基含硫四氮杂卟啉镁[MgPz(S-Bu)8]及其自由配体[H2Pz(S-Bu)8],进而将自由配体与二水合醋酸锌反应得到八正丁硫基四氮杂卟啉锌[ZnPz(S-Bu)8],其化合物的结构通过UV-Vis和NMR的表征。并实验证明[ZnPz(S-Bu)8]具有良好的溶解性,能很好地溶于常见有机溶剂,并且具有耐酸、耐高温和光照稳定性的优点。
Zinc 2,3,7,8,12,13,17,18-octakis（butyl-thio）5,10,15,20 tetraaza porphyrin（ZnPz（S-Bu）8） was synthesized by magnesium as template to react with prepared precursor of MNT（n-Bu）2,as well as characterized by UV-Vis,NMR.Experiments demostrated that the ZnPz（S-Bu）8 had good solubility in ordinary organic solvents,as well as perfomances of acid-resistant,heat-resistant and light fastness.
出处
《化工技术与开发》
CAS
2010年第9期1-3,10,共4页
Technology & Development of Chemical Industry
基金
国家自然科学基金项目(20377053
20577070
20977115)
