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PE-b-PEO嵌段共聚物的合成及其芳烃/烷烃渗透汽化分离性能 被引量：1

Synthesis of PE-b-PEO Block Copolymer and Its Pervaporation Separation of Aromatic/Aliphatic Mixtures
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摘要 采用阴离子聚合方法合成了具有不同环氧乙烷聚合度的聚丁二烯-b-聚环氧乙烷嵌段共聚物(PB-b-PEO嵌段共聚物),然后催化加氢得到聚乙烯-b-聚环氧乙烷嵌段共聚物(PE-b-PEO嵌段共聚物),使用凝胶渗透色谱仪(GPC)、核磁共振氢谱(1H-NMR)对共聚物进行了分析,结果表明所得聚合物具有预定的结构。通过熔融压片的方法制备PE-b-PEO嵌段共聚物均质膜,考察了PE-b-PEO嵌段共聚物分子链中聚环氧乙烷的聚合度对渗透汽化分离性能的影响。 The poly（ethylene-b-ethylene oxide）（PE-b-PEO） block copolymers with various degrees of polymerization for PEO were prepared by hydrogenation of poly（butadiene-b-ethylene oxide） block copolymers（PB-b-PEO）,which were synthesized by anionic polymerization.The copolymers were analyzed by gel permeation chromatography（GPC） and proton nuclear magnetic resonance（^1H-NMR）.The block copolymer membranes were prepared by hot press moulding and were applied in the pervaporation separation of toluene/heptane mixtures.The effect of degree of polymerization for PEO on the performance of the membrane was investigated.
作者 杜玉升 张春庆 李战胜 李扬
机构地区 大连理工大学高分子材料系辽宁省高分子科学与工程重点实验室
出处 《化学工业与工程》 CAS 2010年第5期377-380,386,共5页 Chemical Industry and Engineering
基金 国家自然科学基金资助项目(20874008)
关键词 聚乙烯-b-环氧乙烷嵌段共聚物 阴离子聚合 渗透汽化分离 芳烃/烷烃 PE-b-PEO block copolymer anionic polymerisation pervaporation separation aromatic/aliphatic mixture
分类号 TQ325.12 [化学工程—合成树脂塑料工业]
  • 相关文献

参考文献10

  • 1郭春刚,熊纯青,李战胜,李杨,安小江,张春庆,王玉荣.芳烃/脂肪烃渗透汽化分离膜的研究进展[J].化学工业与工程,2009,26(3):262-267. 被引量：3
  • 2XU W,PAUL D R,KOROS W J.Carboxylic acid containing polyimides for pervaporation separations of toluene/iso-octane mixtures[J].Journal of Membrane Science,2003,219(1/2):89-102.
  • 3CASTILLO R,ARNAL M,MULLER A,et al.Fractionated crystallization and fractionated melting of confined PEO microdomains in PB-b-PEO and PE-b-PEO diblock copolymers[J].Macromolecules,2008,41(3):879-889.
  • 4过俊石,李虹,袁策刚,冯国祥,谢洪泉.(丁二烯-环氧乙烷)多嵌段共聚物的表征及性能[J].高分子学报,1992,2(3):299-304. 被引量：3
  • 5HILLMYER M,BATES F.Synthesis and characterization of model polyalkane-poly(ethylene oxide) block copolymers[J].Macromolecules,1996,29(22):6 994-7 002.
  • 6DENG Y,YOUNG R,RYAN A,et al.Bulk morphology and micellization of poly(diene)-poly(ethylene oxide) diblock copolymers in water[J].Polymer,2002,43(25):7 155-7 160.
  • 7SUN L,LIU Y,ZHU L,et al.Self-assembly and crystallization behavior of a double-crystalline polyethylene-block-poly(ethylene oxide) diblock copolymer[J].Polymer,2004,45(24):8 181-8 193.
  • 8CAO W,KOHJI T,MAKOTO H,et al.Relationship between morphological change and crystalline phase transitions of polyethylene-poly(ethylene oxide) diblock copolymers,revealed by the temperature-dependent synchrotron WAXD/SAXS and infrared/Raman spectral measurements[J].The Journal of Physical Chemistry B,2009,113(8):2 338-2 346.
  • 9陶绪泉,谢洪泉.(苯乙烯-丁二烯-环氧乙烷)多嵌段共聚物的合成及表征[J].功能高分子学报,1992,5(1):59-64. 被引量：2
  • 10TANAKA Y.Characterization of diene polymers.Ⅰ.Infrared and NMR studies:Nonadditive behavior of characteristic infrared bands[J].Journal of Polymer Science Part A-2:Polymer Physics,1971,9(1):43-57.

二级参考文献45

  • 1方志平,姜忠义.苯-环己烷分离渗透蒸发膜的研究进展与展望[J].石油化工,2005,34(9):885-890. 被引量：10
  • 2JONQUIERES A,CLEMENT R,LOCHON P,et al.Industrial state-of-the-art of pervaporation and vapour permeation in the western countries[J].J Membr Sci,2002,206(1/2):87-117.
  • 3SHAO P,HUANG R Y M.Polymeric membrane pervaperation[J].J Membr Sci,2007,287(2):162-179.
  • 4GARCIA VILLALUENGA J P,TABE-MOHAMMADI A.Areview on the separation of benzene/cyclohexane mixtures by pervaporation processes[J].J Membr Sci,2000,169(2):159-174.
  • 5MEINDERSMA G W,de HAAN A B.Economical feasibility of zeolite membranes for industrial scale separations of aromatic hydrocarbons[J].Desalination,2002,149(1/3):29-34.
  • 6KOROS W J.Membranes:Learning a lesson from nature[J].Chem Eng Prog,1995,91(10):68-81.
  • 7SARTORI G,WINSTON HO W S.Polyester membranes for aromatics/saturates separation:US,4976868[P].1990-12-11.
  • 8SARTORI G,WINSTON Ho W S,SAVAGE D W,et al.Non-porous polycarbonate membranes for separation of aromatics from saturates:US,5019666[P].1991-05-28.
  • 9HAO J,TANAKA K,KITA H,et al.The pervaporation properties of sulfonyi-containing polyimide membranes to aromatic/aliphatic hydrocarbon mixtures[J].J Membr Sci,1997,132(1):97-108.
  • 10WANG H,UGOMORI T,TANAKA K,et al.Sorptian and pervaporation properties of su]fonyl-containing pelyimide membrane to aromatic/non-aromatic hydrocarbon mixtures[J].J Polym Sci,PartB:Polym Phys,2000,38(22):2954-2964.

共引文献5

同被引文献14

  • 1Lu S, Liu Y, Zhu L, et al. Sell-assembly and crystallization behavior of a double-crystalline polyethylene-block-poly (ethylene oxide) diblock copolymer[J]. Polymer, 2004, 45 (24) : 8181-8193.
  • 2Cao W, Tashiro K, Hancsaka M, et al. Relationship between morphological change and crystalline phase transitions of polyethylene-poly ( ethylene oxide ) diblock copolymers, revealed by the temperature-dependent synchrotron wzxd/saxs amt infrared/raman spectral measurements[J]. The Journal of Physical Chemistry. B, 2009, 113 ( 8 ) : 2338-2346.
  • 3Castillo R V, Arnal M L, M tiller A J, et al. Fractionated crystallization and fractionated melting of confined PEO microdomains in PB-b-PEO and PE-b-PEO diblock cepolymers[J]. Macromolecules, 2008, 41 (3) : 879-889.
  • 4Hilhnyer Marc A, Frank S Bates. Synthesis and characterization of model polyalkmae-poly ( ethylene oxide ) block copolymers[J].Macromolecules, 1996, 29 ( 22 ) : 6994-7002.
  • 5Jain S, Bates Frank S. Consequences of nonergodicity in aqueous binary PEO-PB micellar dispersions[J]. Macromolecules, 2004, 37 (4) :1511-1523.
  • 6Esswein B, M~ller M. Polymerization of ethylene oxide with alkyllithium compounds and the phosphazene base"tBu-P4" [J]. Angew Chem Int Ed, 1996, 35 ( 6 ) : 623-625.
  • 7Floudas G, Vazaiou B, Schipper F, et al. Poly (ethylene oxide-b-isoprene ) diblock copolymer phase diagram[J]. Macromolecules, 2001, 34 (9) : 2947-2957.
  • 8Schmalz H, Knoll A, Muller A J, et al. Synthesis and characterization of abc triblock copolymers with two different crystalline end blocks: influence of confinement on crystallization behavior and morphology[J]. Macromolecules, 2002, 35 (27) , 10004-10013.
  • 9Rejsek ~, Desbois P, Deffieux A, et at. Polymerization of ethylene oxide initiated by lithium derivatives via the monomer-activated approach: application to the direct synthesis of PS-b-PEO and PI-b-PEO diblock copolymers[J]. Polymer, 2010, 51 (24) : 5674-5679.
  • 10Kotzabasakis V, Georgopoulou E, Pitsikalis M, et al. Catalytic conversions in aqueous media: a novel and efficient hydrogenation of polybutadiene-1,4-block-poly ( ethylene oxide ) catalyzed by rh/tppts complexes in mixed mieellar nanoreactors[J]. Journal of Molceular Catalysis A: Chemical, 2005, 231 (1/2) :93-101.

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化学工业与工程
2010年 第5期

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