杂多蓝的结构及其光化学研究进展

Developments in the Structure and Photochemistry of Heteropoly Blue

本文介绍了关于杂多蓝(HPB)的结构及其光化学的最新研究进展,特别对新型结构HPB的合成、电子结构的计算化学、光致还原反应制备新型纳米金属材料、有机-无机光致变色复合薄膜、HPB对半导体材料的协同与敏化作用、以及特殊结构的HPB在光化学反应中的应用重点进行了阐述,并就合成新型结构杂多酸进而调变杂多蓝性质,及它们在光化学领域中的应用进行了展望。

The developments in the structure and photochemistry of heteropoly blue （HPB） are reviewed, including the synthesis of new type HPB, the analysis of electron structure of HPB with calculational chemistry, the photo-induced reduction of heteropoly blue, preparing of novel nanostructure metal materials, organicinorganic hybrid photochromic films, HPB′ s synergistic function and sensitization for semiconductor, and utilization of HPB with special structure in photochemistry etc. Prospects are also pointed out for fabricating novel heteropoly acids to modify the properties of HPB for their further employment in photochemistry