一维链状镍髤配合物[Ni(L)(Mf)]n的合成、晶体结构及电化学性质(英文) 被引量：3

Synthesis, Crystal Structure and Electrochemical Property of 1D Chain Complex [Ni(L)(Mf)]_n

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摘要合成了1个含2-羟基苯乙酮缩水杨酰腙(H2L)和单齿N-杂环分子吗啡啉(Mf)的镍髤配合物[Ni(L)(Mf)]n,并通过元素分析、紫外光谱、热分析以及单晶衍射等手段进行表征。在配合物中,中心Ni髤与酰腙配体的酚氧、亚胺氮、去质子酰胺氧原子以及中性吗啡氮原子配位形成平面四方形的N2O2配位构型。配合物通过N-H(吗啡)…O(吗啡)分子间氢键作用构筑成一维超分子网络结构。采用循环伏安法研究了化合物的电化学性质。 A nickel（Ⅱ） complex [Ni（L）（Mf）]n with 2-hydroxyacetophenone salicyloylhydrazone （H2L） and monodentate N-donor heterocycle, morpholine （Mf） has been synthesized and characterized by elemental analysis, UV, TG and X-Ray diffraction. In the complex, the Ni（Ⅱ） ion is in a square-planar N2O2 coordination geometry formed by the phenolate-O, the imine-N and the deprotonated amide-O atoms from L2-, and the N atom of neutral morpholine. In the crystal, a one-dimensional supramolecular network structure is formed via N-H（morpholine） …O（morpholine） intermolecular hydrogen bonds. The electrochemical property was studied with an electrochemical analyzer.

作者陈小华吴琼洁陈顺玉黄淑梅江飞凤

机构地区福建师范大学化学与材料学院福建农林大学生命科学学院

出处《无机化学学报》 SCIE CAS CSCD 北大核心 2010年第9期1573-1576,共4页 Chinese Journal of Inorganic Chemistry

基金福建师范大学本科生“课外科技计划”项目(NoBKL2009045)资助

关键词镍髤配合物 SCHIFF碱晶体结构电化学性质 nickel（Ⅱ） complex Schiff base crystal structure electrochemical property

分类号 O614.813 [理学—无机化学]

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