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饮用水中致癌物质卤乙酸(HAAs)测定解析

Approach to the analysis method of haloacetic acids (HAAs) in drinking water
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摘要 目的建立饮用水中氯消毒副产物卤乙酸的测定方法。方法采用气相色谱法,微电子捕获检测器(如安捷伦6890型),色谱柱为DB-5,30m×0.25mm×0.25μm,改进了原方法的升温程序和预处理过程。结果色谱图分离效果好,线性关系良好(R2>0.999),检出限低。结论本法简单、安全、可行、易于推广。 Objective To establish a method for determination of haloacetic acids(HAAs) in water.Methods Gas Chromatograph,with a micro ECD(Agilent Model 6890),GC column-DB-5,30-meter length,0.25-mm i.d.,0.25-μm film,the modification made to temperature program and sample procedure.Results The chromatogram shows well isolated peaks of HAAs,calibration curves of high linearity were obtained in all cases(R20:999),the detection limits were low.Conclusion This method was simpler,safer,more feasible.
出处 《中国现代医药杂志》 2010年第9期62-64,共3页 Modern Medicine Journal of China
基金 国家高科技研究发展计划(863计划)项目(2002AA601120) 内蒙古工业大学科学研究基金项目(X200705)
关键词 卤乙酸 饮用水 致癌物质 测定方法 HAAs Drinking water Carcinogens Analysis method
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参考文献3

  • 1Singer PC.Formation and control of disinfection by-products in drinking water.AWWA,1999.
  • 2USEPA.Method552.3:Determination of Haloacetic Acids and Dalapon in Drinking Water by Liquid-Liquid Microextractior,Derivatization,and Gas Chromatography with Electron Capture De tection.USEPA,2003.
  • 3刘文君,贺北平,曹莉莉,李爽,张晓健,王占生.饮用水中消毒副产物卤乙酸(HAAs)测定方法研究[J].给水排水,2004,30(8):38-41. 被引量:18

二级参考文献5

  • 1Singer P C. Formation and control of disinfection by-products in drinking water. AWWA,1999
  • 2USEPA (1998) National Primary Drinking Water Regulations:Disinfectants and Disinfection By-Products,Final Rule. Fed Reg,63(241): 69389
  • 3Barth R C,Fair P S. Comparison of the microextraction procedure and method 552 for the analysis of HAA and chlorophenols.AWWA,1992,84(11): 94-98
  • 4APHA-AWWA-WEF. ( 6251 ) Disinfection by-products: Haloacetic acids and trichlophenol. Standard Methods for the Examination of Water and Wastewater. 19th Ed. Washington D C,1995
  • 5Xie Y,Reckhow D A,et al. Analyzing HAAs and ketoacids without diazomethane. AWWA,1998,90(4): 131-138

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