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一种锁链型配位聚合物[Cu(dpp)_2bpdc]_n的合成与晶体结构 被引量：2

SYNTHESIS AND CRYSTAL STRUCTURE OF A NEW IRON CHAIN-LIKE COORDINATION POLYMER [Cu_2(dpp)_2bpdc]_n
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摘要 以1,3-二(4-吡啶基)丙烷(1,3-Di(4-pyridyl)propane,dpp)和4,4'-联苯二甲酸(4,4'-Biphenyldicarboxylic acid,bpdc)混合配体与硝酸铜经水热反应合成了配位聚合物[Cu(dpp)bpdc]n。晶体结构分析表明,[Cu(dpp)bpdc]n为一锁链型配位聚合物,锁链之间通过分子间的C—H…π相互作用形成三维超分子结构。 In this paper, the coordination polymer [Cu2（dpp）2bpdc]n was synthesized by the hydrothermal reaction using copper nitrate and the mixed ligands of 1,3-di（4-pyridyl）propane （dpp） and 4,4＇- Biphenyldicarboxylic acid （bpdc）. The crystal structural analysis showed that [Cu2（dpp）2bpdc]n is a iron chain-like coordination polymer, and the different chain are hold together by the intermolecular C—H…π interactions to form three-dimensional supramolecular structure.
作者 隋岩 胡荣华 张新宏
机构地区 井冈山大学化学化工学院
出处 《井冈山大学学报（自然科学版）》 2010年第5期46-49,共4页 Journal of Jinggangshan University (Natural Science)
基金 江西省教育厅科技项目(GJJ10536) 江西省自然科学基金项目(2007GZH1667)
关键词 1 3-二(4-吡啶基)丙烷 4 4'-联苯二甲酸 配合物 超分子 1 3-Di（4-pyridyl）propane 4 4＇-Biphenyldicarboxylic acid complex supramolecular
分类号 O641 [理学—物理化学]
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参考文献16

  • 1Yaghi O M,Davis C E,Li G M,et al.Selective Guest Binding by Tailored Chan-nels in a 3-D Porous Zinc(II)-Benzenetricarboxylate Network[J].J.Am.Chem.Soc,1997,119:2861-2868.
  • 2Noro S,Kitagawa S,Kondo M,et al.A New,Methane Adsorbent,Porous Coordi-nation Polymer[{CuSiF6(4,4'-bipyridine)2}n] [J].Angew.Chem.Int.Ed.,2000,39:2082-2084.
  • 3Bennett M V,Shores M P,Beauvais L G,et al.Expansion of the Porous Solid Na2Zn3[Fe(cn)6] 2·9H2O:Enhanced Lon-Exchange Capacity in Na2Zn3[Re6Se8(cn)6] 2·24H2O[J].J.Am.Chem.Soc.,2000,122:6664-6668.
  • 4Seo J S,Whang D,Lee H,et al.A Homochiral Metal-organic Porous Material for Enantioselective Separation and Catalysis[J].Nature,2000,404:982-986.
  • 5Hoskins B F,Robson R.Design and Construction of a New Class of Scaffolding-like Materials Comprising Infinite Polymeric Frameworks of 3D-Linked Molecular Rods.A Reappraisal of the Zn(CN)2 and Cd(CN)2 Structures and the Synthesis and Structure of the Diamond-Related Frameworks[N(CH3)4] [CuIZnII(CN)4] and CuI[4,4″4″,4″′-tetracy anotetraphenylmethane] BF4·xC6H5NO2[J].J.Am.Chem.Soc.,1990,112:1546-1554.
  • 6Barnett S A,Champness N R.Structural Diversity of Building-blocks in Coordination Framework Synthesis-combining M(NO3)2 Junctions and Bipyridyl Ligands[J].Coord.Chem.Rev.,2003,246:145-168.
  • 7Kitagawa S,Masaoka S.Metal Complexes of Hexaazatriphenylene (hat) and Its Derivatives from Oligonuclear Complexes to Coordination Polymers[J].Coord.Chem.Rev.,2003,246:73-88.
  • 8Biradha K,Sarkar M,Rajput L.Crystal Engineering of Coordination Polymers Using 4,4'-bipyridine as a Bond between Transition Metal Atoms[J].Chem.Commun,2006:4169-4179.
  • 9Hagrman P J,Zubieta J,Hagrman D.Organic-Inorganic Hybrid Materials:From "Simple" Coordination Polymers to Organodiamine-Templated Molybdenum Oxides[J].Angew.Chem.Int.Ed.,1999,38:2638-2684.
  • 10Holliday B J,Mirkin C A.Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry[J].Angew.Chem.Int.Ed.,2001,40:2022-2043.

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井冈山大学学报（自然科学版）
2010年 第5期

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