摘要
To understand the aging effects on detonation performances of explosives,an accelerated aging mechanism and effect of explosives were analyzed.Based on the thermo-gravimetric(TG) curves of explosives under the heat rate of 5,10 and 20 K·min-1,the thermal decomposition activation energy,pre-exponential factor,mechanism function and kinetic equation of the explosives were calculated by Ozawa's equation and decomposition extents.Then,according to the derived kinetic equation,the density,composition and heat of formation of GI-1,PBX-1 and PBX-2 explosive in different decomposition extents were calculated at accelerated aging temperatures of 70 ℃ and 75 ℃,respectively.Furthermore,the detonation parameters of GI-1,PBX-1 and PBX-2 explosives were found out by means of VLWR code.The results show that after accelerated aging,the density are decrease,the detonation velocity and pressure are all decreased slightly.
To understand the aging effects on detonation performances of explosives, an accelerated aging mechanism and effect of explosives were analyzed. Based on the thermo-gravimetric （TG） curves of explosives under the heat rate of 5, 10 and 20 K·min^-1 , the thermal decomposition activation energy, pre-exponential factor, mechanism function and kinetic equation of the explosives were calculated by Ozawa＇s equation and decomposition extents. Then, according to the derived kinetic equation, the density, composition and heat of formation of GI-1, PBX-1 and PBX-2 explosive in different decomposition extents were calculated at accelerated aging temperatures of 70℃ and 75℃, respectively. Furthermore, the detonation parameters of GI-1, PBX-1 and PBX-2 explosives were found out by means of VLWR code. The results show that after accelerated aging, the density are decrease, the detonation velocity and pressure are all decreased slightly.
