过渡金属苯丙氨酸希夫碱配合物的合成及表征

Synthesis and Characterization and Catalytic Oxidation of N-Salicylidenephenylalanine Acid with Transition Metals Complexes

合成了５ 种苯丙氨酸希夫碱过渡金属配合物Ｍｎ（Ｓａｌ－ Ｐｈｅ）、Ｆｅ（Ｓａｌ－ Ｐｈｅ） 、Ｃｏ（Ｓａｌ－ ｐｈｅ） 、Ｎｉ（Ｓａｌ－ Ｐｈｅ）、Ｃｕ（Ｓａｌ－ Ｐｈｅ），对配合物进行了热重－ 差热分析、红外光谱分析、ＸＰＳ分析，测定了配合物的金属含量（ＩＣＰ） 。

Five complexes of N-Salicylideneamino acid transition metals were synthesized,and they were SalPheCo、SalPheMn、SalPheNi、SalPheCu、SalPheFe.The structure of the complexes were characterized by thermogravimetric and differential thermal analysis、infrared,small area X-ray photoelectron spectroscopy(XPS)and ICP-AES.