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基于烷基锌催化的不对称Henry反应研究进展 被引量：4

Research Progress in Catalytic Asymmetric Henry Reaction Based on Alkylzinc Reagents
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摘要 Henry反应是一类有效的碳碳键形成反应,其产物邻硝基醇可进一步转化为含氮、氧原子的有机中间体.根据催化剂的结构类型对基于烷基锌金属络合催化的不对称Henry反应进行了综述. A review is provided of research progress in asymmetric Henry reaction based on alkylzinc reagents in relation to structure types of chiral catalysts.It is pointed out that Henry reaction is one of the powerful carbon-carbon bond formation reactions;the resulting product of the reaction,β-nitroalcohol,can be transformed into a number of nitrogen-and oxygen-containing derivatives.
作者 李高伟 赵文献 郭蕊 刘新明 郭保国 王敏灿
机构地区 商丘师范学院化学系商丘师范学院有机新材料合成重点实验室 郑州大学化学系河南省化学生物与有机化学重点实验室
出处 《化学研究》 CAS 2010年第5期107-112,共6页 Chemical Research
基金 国家自然科学基金(20972091)资助项目
关键词 Henry反应 β-硝基醇 烷基锌 研究进展 Henry reaction β-nitroalcohol alkyl zinc research progress
分类号 O646.1 [理学—物理化学]
  • 相关文献

参考文献16

  • 1Henry L,Hebd C R.Formation synthétique dàkool nitzés[J].C R Hebd Seances Acad Sci,1895,120:1265-1268.
  • 2Henry L.Formation synthétique dàkool nitzés[J].Bull Sci Chim Paris,1895,13:999-1003.
  • 3Trost B M,Lupton D W.Dinuclear zinc-catalyzed enantioselective aza-Henry reaction[J].Org Lett,2007,9(10):2023-2026.
  • 4Boruwa J,Gogoi N,Saikia P P,et al.Catalytic asymmetric Henry reaction[J].Tetrahedron:Asymmetry,2006,17(24):3315-3326.
  • 5Palomo C,Oiarbide M,Laso A.Recent advances in the catalytic asymmetric nitroaldol (Henry) reaction[J].Eur J Org Chem,2007,2007(16):2561-2574.
  • 6雷厉军,何煦昌.不对称Henry反应的研究进展[J].合成化学,2006,14(1):7-13. 被引量：3
  • 7甘昌胜,潘见.不对称催化Henry反应研究进展[J].有机化学,2008,28(7):1193-1198. 被引量：7
  • 8Trost B M,Yeh V S C.A dinuclear Zn catalyst for the asymmetric nitroaldol (Henry) reaction[J].Angew Chem Int Ed,2002,41 (5):861-863.
  • 9Klein G,Pandiaraju S,Reiser O.Activation of nitroaldol reactions by diethylzinc and amino alcohols or diamines as promoters[J].Tetrahedron Lett,2002,43 (42):7503-7506.
  • 10Zhong Y W,Tian P,Lin G Q.New β-amino alcohols with a bicyclo[3.3.0]octane scaffold in an asymmetric Henry reaction[J].Tetrahedron:Asymmetry,2004,15(5):771-776.

二级参考文献65

  • 1Henry L,Hebd C R.Formation synthétique dákoolnitzés[ J ].C R Hebd Seances Acad Sci,1895,120:1265-1268.
  • 2Wehner V,Jager V.Synthesis of D-and L-2-amino2-deoxyarabinose and 1,4-dideoxy-1,4-iminolyxitol by (C2+C3)-nitroaldol addition with 2-O-benzylglyceraldehyde t[ J ].Angew Chem Int Ed,1990,29 (10):1169-1171.
  • 3Hanessian S,Devasthale P V.Generation of functional diversity via nitroaldol condensations of α-aminoacid aldehydes--A new and stereocontrolled route to acyclic 1,3-diamino-2-alcohols [ J ].Tetrahedron Letters,1996,37 (7):987-990.
  • 4Kubyda I,Raczko J,Jurczak J.Asymmetric nitroaldol reaction.Synthesis of taxotere side chain and (-)-bestatin using (1 R)-8-phenylmenthyl glyoxylate[J].J Org Chem,2004,69(8):2844-2850.
  • 5Christensen C,Juhl K,Jorgensen K A.Catalyticasymmetric henry reactions-a simple approach to optically active β-nitro α-hydroxy esters [ J ].Chem Commun,2001:2222-2223.
  • 6Knudsen K R,Risgaard T,Nishiwaki N,et al.The first catalytic asymmetric aza-henry reaction of nitronates with imines:A novel approach to optically activeβ-nitro-α-amino acid-and,β-diamino acid derivatives [J].J Am Chem Soc,2001,123(24):5843-5844.
  • 7Henry L.Formation synthétique dákool nitzés [ J ].Bull Sci Chim Paris,1895,13:999-1003.
  • 8Rosini G.Comprehensive Organic Synthesis[M].Vol.2,Ed:Trost B M,New York:Pergamon,1991:321-340.
  • 9Ono N.The Nitro Group In Organic Synthesis [ M ].New York:Wiley-Vch,2001:Chapter 3.
  • 10Luzzio F A.The Henry reaction:recent examplees[ J].Tetrahedron,2001,57:915-945.

共引文献7

同被引文献64

  • 1王敏灿,王德坤,娄建平,华远照.Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes[J].Chinese Journal of Chemistry,2004,22(6):512-514. 被引量：6
  • 2范宁娟,郭炜,夏炽中.水介质中Zn-脯氨酸催化的Henry反应研究[J].山西大学学报（自然科学版）,2005,28(3):283-285. 被引量：1
  • 3Trost B M, Malhotra S, Mino T, Rajapaksa N S. Chem. Eur. J. , 2008,14: 7648-7657.
  • 4Dodd K, Morton D, Worden S, Narquizian R, Nelson A. Chem. Eur. J. , 2007, 13: 5857 -5861.
  • 5XiaoY L, Wang Z, Ding K L. Chem. Eur. J., 2005, 11: 3668-3678.
  • 6Xiao Y L, Wang Z, Ding K L. Macromolecules, 2006, 39: 128-137.
  • 7Rozners E, Fontanez J. Letters in Organic Chemistry, 2005, 2: 524-527.
  • 8Pedersen C J, Frensdorff H K. Angew. Chem. Int. Ed. Engl. , 1972, 84: 16-26.
  • 9Cram D J, Sogah G D Y. J. Chem. S0c. Chem. Commun., 1981, 625-628.
  • 10Cram D J, Sogah G D Y. J. Am. Chem. S0c., 1985, 107: 8301-8302.

引证文献4

二级引证文献2

化学研究
2010年 第5期

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