摘要
应用碘化钾显色和紫外可见分光光度法，在２０℃下研究了亚铁－组氨酸配合物与亚铁－三乙烯四胺模拟过氧化氢酶催化过氧化氢分解反应．提出了一种金属配合物催化的数学模型．计算结果表明，金属离子的恰当配位体的络合作用。
The Fe(Ⅱ) Complexes (Fe(Ⅱ) His,Fe(Ⅱ) trien) were constructed for simulating catalase.Using KI color and UV spectrophotometry,the catalytic decomposition of hydrogen peroxide was studied at 20℃ by the Fe(Ⅱ) complexes.A model of metal complex catalysis was suggested.The calculated results from this model indicate that a suitable complex for metal ion is very important in getting a effective metal complex catalyst.
出处
《四川大学学报（自然科学版）》
CAS
CSCD
北大核心
1999年第2期315-319,共5页
Journal of Sichuan University(Natural Science Edition)
基金
国家自然科学基金
关键词
亚铁配合物
人工酶
过氧化氢酶
模拟
Fe(Ⅱ) consplex
artificial enzyme
decomposition of hydrogen peroxide
catalase
simulation
