大环内酯类糖苷的合成研究

Synthesis of Macrolide Glucoside

根据威灵仙中环二酯类糖苷化合物的结构特点,以2,3,4-三苄基-6-酰基葡萄糖为原料,利用分步聚合的策略,完成了对二聚物模型的合成.产物结构经1HNMR,13CNMR和HRMS确证.

In terms of the structure of macrolide glucoside in radix clematides,model dimer was synthesized from 2,3,4-tri-O-benzyl-6-O-acetyl-D-glucopyranose with our originate fractional polymerization. The products were identified by 1H NMR,13C NMR and HRMS techniques.