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氢氧化铁对水中砷的吸附试验研究 被引量:6

Adsorption of As(Ⅲ) from water by ferric hydroxide
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摘要 就氢氧化铁对As(Ⅲ)的吸附动力学、吸附等温线以及pH和温度等影响因素进行了研究。结果表明:氢氧化铁对As(BI)的吸附动力学符合Lagergren二级吸附动力学模型,其吸附等温线可用Langmuir方程很好地描述,即属于单分子层吸附,试验得到的饱和吸附量为9.09mg/g;pH值在4.1~8.5内,氢氧化铁对As(Ⅲ)的去除率较高,保持在70%以上,超出这个范围,氢氧化铁对As(Ⅲ)的去除率逐渐降低,pH值为6.8左右时,氢氧化铁对As(III)的去除率达到最高,约为94.8%;随着温度的升高,氢氧化铁对As(Ⅲ)的吸附率逐渐降低,在0~25℃时,氢氧化铁对As(Ⅲ)的去除率保持在80%以上。 The adsorption of As (Ⅲ) using ferric hydroxide was investigated, concerning with the adsorption kinetics, adsorption isotherm, influencing factors of pH and temperature. The result showed that the adsorption of As (Ⅲ) by ferric hydroxide conformed to the second order Langmuir adsorption kinetic model, the adsorption isotherm could be well described with the Langmuir equation, this kind of adsorption was single-module layer adsorption, and the saturation adsorption capacity was 9.09 mg/g. When pH ranged from 4.1 to 8.5, the removal rate of As (Ⅲ) maintained above 70% , beyond this scope the removal rate decreased. When pH was about 6.8, the removal rate of As (Ⅲ ) using ferric hydroxide was the largest, that was 94.8%. With the temperature increasing, the removal rate of As ( Ⅲ ) was gradually reduced, the removal rate of As (Ⅲ) using ferric hydroxide remained above 80% at 0 to 25 ℃.
出处 《供水技术》 2010年第5期17-20,共4页 Water Technology
关键词 氢氧化铁 As(Ⅲ) 吸附 除砷 ferric hydroxide As (Ⅲ) adsorption arsenic removal
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参考文献7

  • 1Kaltreider R C,Davis A M,Lariviere J P,et al.Arsenic alters the function of the glucocorticoid receptor as a transcription factor[J].Environ Health Perspect,2001,109(3):245-251.
  • 2Report on the expert panel on arsenic carcinogenicity:review and workshop[R].Washington DC:National Center for Envionmental Assessment,USEPA,1997.
  • 3常方方,曲久辉,刘锐平,刘会娟,雷鹏举,张高生,武荣成.铁锰复合氧化物的制备及其吸附除砷性能[J].环境科学学报,2006,26(11):1769-1774. 被引量:64
  • 4Grossl P R,Eick M,SparksD L,et al.Arsenate and chromate retention mechanisms on goethite:kinetic evaluation using a pressure-jump relaxation technique[J].Environ Sci Technol,1997,31(2):321-326.
  • 5Fendorf S,Eick M J,Grossl P R,et al.Arsenate and chromate retention mechanisms on goethite:surface structure[J].Environ Sci Technol,1997,31(2):315-320.
  • 6马红梅,朱志良,张荣华,赵建夫.β-FeO(OH)对水中砷的吸附作用[J].同济大学学报(自然科学版),2007,35(12):1656-1660. 被引量:22
  • 7Mondala P,Majumder C B,Mohantya B.A laboratory study for the treatment of arsenic,iron,and manganese bearing ground water using Fe^3+ impregnated activated carbon:effects of shaking time,pH and temperature[J].J Hazard Mater,2007,144(1-2):420-426.

二级参考文献29

  • 1Agusa T, Kunito T, Fujihara U, et al. 2006. Contamination by arsenic and other trace elements in tube-well water and its risk assessment to humans in Hanoi, Vietnam [J]. Environmental Pollution, 139:95-106.
  • 2Bundschuh J, Farias B, Martin R, et al. 2004. Groundwater arsenic in the Chaco-Pampean Plain, Argentina: case study from Robles county, Santiago del Estero Province [J]. Applied Geochemistry, 19:231-243.
  • 3Dixit S, Hering J G. 2003. Comparison of Arsenic(Ⅴ) and Arsenic(Ⅲ) Sorption onto Iron Oxide Minerals: Implications for Arsenic Mobility [J]. Environmental Science & Technology, 37:4182-4189.
  • 4Karim M D Masud. 2000. Arsenic in groundwater and health problems in Bangladesh [J]. Water Research, 34:304-310.
  • 5Kohn T, Kenneth J T, Roberts A L, et al. 2005. Longevity of Granular Iron in Groundwater Treatment Processes : Corrosion Product Development [J]. Environmental Science & Technology, 39: 2867-2879.
  • 6Lee Y, Um I, Yood J. 2003. Arsenic (Ⅲ) Oxidation by Iron (Ⅵ) (Ferrate) and Subsequent Removal of Arsenic (Ⅴ) by Iron (Ⅲ) Coagulation [J]. Environmental Science & Technology,37:5750-5756.
  • 7Lenoble V, Laclautre C, Serpaud B, et al. 2004. As(Ⅴ) retention and As (Ⅲ) simultaneous oxidation and removal on a MnO-loaded polystyrene resin [J]. Science of the Total Environment, 326: 197-207.
  • 8Lin T F, Wu J K. 2001. Adsorption of arsenite and arsenate within activated alumina grains: equilibrium and kinetics [J]. Water Research, 35 : 2049-2057.
  • 9Meng X G, Korfiatis G P, Bang S, et al. 2002. Combined effects of anions on arsenic removal by iron hydroxides [J]. Toxicology Letters, 133:103-111.
  • 10Rahmana M M, Senguptaa M Kr, Ahameda S. 2005. The magnitude of arsenie contamination in groundwater and its health effects to the inhabitants of the Jalangi-one of the 85 arsenic affected blocks in West Bengal, India [J]. Science of the Total Environment, 338: 189-200.

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