摘要
Urease-loaded colloidosome microcapsules with SiO2 nanoparticle shells and gellan gel cores were prepared facilely and highly efficiently by self-assembly of colloidal particles at the liquid-liquid interfaces and subsequently in-situ gelation of gellan gum. The urease-loaded colloidosome microcapsules were used as an enzymatic reactor to produce calcium carbonate precipitates by urease-catalyzed urea hydrolysis in the presence of calcium cations. The CaCO3/SiO2 shells were formed finally around the gellan gel cores. The colloidosome microcapsules used as a biomimetic reactor has been demonstrated for the first time.
Urease-loaded colloidosome microcapsules with SiO2 nanoparticle shells and gellan gel cores were prepared facilely and highly efficiently by self-assembly of colloidal particles at the liquid-liquid interfaces and subsequently in-situ gelation of gellan gum. The urease-loaded colloidosome microcapsules were used as an enzymatic reactor to produce calcium carbonate precipitates by urease-catalyzed urea hydrolysis in the presence of calcium cations. The CaCO3/SiO2 shells were formed finally around the gellan gel cores. The colloidosome microcapsules used as a biomimetic reactor has been demonstrated for the first time.
基金
Supported by the National Natural Science Foundation of China(Nos.20874030 and 50973034)
the Chinese Universities Scientific Fund(No.2009ZZ0036)
the Planned Science and Technology Project of Guangdong Province, China(No.2010B010800017)
