摘要
SiO2 aerogels were produced from tetraethyl orthosilicate （TEOS） as silicon resources,ethanol as solvent and watery HCl or ammonia by sol-gel method and surface modification at ambient pressure.Scanning electronic microscopy,Fourier transform infrared spectrometer （FT-IR）,pore size distribution measurement,packing density and some other experiment methods were used to characterize the morphology and pore structure and other properties of the silica aerogels.The results show that the silica aerogels have a typical nano-porous microstructure with hydrophobic property.It was discovered that SiO2 aerogels have better properties when the preparation condition is as following the watery HCl concentration is 1%,the aging reagent is CH3CHOHC4H9,the aging time is 20 d,the volume concentration of trimethylchlorosilane （TMCS） in hexane is 6% and the surface modification time is 24 h.
SiO2 aerogels were produced from tetraethyl orthosilicate （TEOS） as silicon resources,ethanol as solvent and watery HCl or ammonia by sol-gel method and surface modification at ambient pressure.Scanning electronic microscopy,Fourier transform infrared spectrometer （FT-IR）,pore size distribution measurement,packing density and some other experiment methods were used to characterize the morphology and pore structure and other properties of the silica aerogels.The results show that the silica aerogels have a typical nano-porous microstructure with hydrophobic property.It was discovered that SiO2 aerogels have better properties when the preparation condition is as following the watery HCl concentration is 1%,the aging reagent is CH3CHOHC4H9,the aging time is 20 d,the volume concentration of trimethylchlorosilane （TMCS） in hexane is 6% and the surface modification time is 24 h.
基金
Sponsored by the National Research Fund for Fundamental Key Projects (2002CB211800)
Project of Beijing Key Laboratory of Environmental Science and Engineering (SYS100070416)
