摘要
The isotherm,mechanism and kinetics of carbon tetrachloride(CT) adsorption by polyacrylonitrile-based activated carbon fiber(PAN-ACF) were investigated in batch reactors and a continuous flow reactor,and the regeneration of PAN-ACF was also studied.Freundlich and Dubinin-Radushkevich(D-R) adsorption equations can well describe the adsorption isotherm.CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion.The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model,and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model.The ACF can be recycled through thermal regeneration,whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration.78%-94%of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale,which confirms the efficacy of ACF under industrial conditions.The results indicate that PAN-ACF is applicable to CT removal from wastewater.
The isotherm, mechanism and kinetics of carbon tetrachloride （CT） adsorption by polyacrylonitrile-based activated carbon fiber （PAN-ACF） were investigated in batch reactors and a continuous flow reactor, and the regeneration of PAN-ACF was also studied. Freundlich and Dubinin-Radushkevich （D-R） adsorption equations can well describe the adsorption isotherm. CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion. The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model, and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model. The ACF can be recycled through thermal regeneration, whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration. 78%-94% of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale, which confirms the efficacy of ACF under industrial conditions. The results indicate that PAN-ACF is applicable to CT removal from wastewater.
基金
Project(2004C33068) supported by the Science and Technology Programs of Zhejiang Province,China
Project(20100933B17) supported by the Social Development and Science Research Program of Hangzhou,China
