Ne与H_2^+/HD^+/HT^+反应的同位素效应

The isotopic effect of the reactions Ne+H_2^+/HD^+/HT^+

基于Lv等人的势能面,运用准经典轨线方法,在入射碰撞能为1.7eV时,对Ne+H2+及其同位素取代反应的立体动力学性质进行了研究.对反应的k-j′两矢量相关和k-k′-j′三矢量相关进行了详细的讨论.结果表明此入射能量下出现了与0.7eV反应类似的同位素效应.

The stereodynamics of the reaction Ne＋H2＋ and its isotopic variants at the collision energy of 1.7eV have been studied by means of the quasi-classical trajectory method based on the potential energy surface constructed by Lv et al.The vector correlation of k-k′ and k-k′-j′ have been discussed in detail.The results show that the reactions have obvious isotopic effects similar to those at the collision energy of 0.7eV.