摘要
采用"组合激光溅射制膜技术",制备了高质量(La1-xCax)VO3(0≤x≤1)成分梯度薄膜。采用组合热电测量系统和组合XRD系统测量了(La1-xCax)VO3(0≤x≤1)成分梯度薄膜的热电性能和晶体结构。在0≤x≤1范围内,(La1-xCax)VO3形成了固溶体。800℃生长的LaVO3薄膜具有最大的功率因数(α)值0.6μW/cm K2。V离子化学价对LaVO3的热电性能影响很大,当它由+3向+2变化时,可能获得良好的热电性能。
La1-xCaxVO3 composition-spread films were fabricated by combinatorial pulsed laser deposition and their thermoelectric properties were evaluated paralelly by the multi-channel thermoelectric measurement system.Concurrent X-ray analysis verified the formation of solid soluted films in the full composition range(0≤x≤1) as judged from the linear variation of the lattice constants.The power coefficient of 0.6 μW/cm K2 was achieved in LaVO3 film at 800℃.Large TE properties in vanadium oxide system can be expected with the change of vanadium ion valence from 3+ to 2+.
出处
《材料开发与应用》
CAS
2010年第5期64-68,共5页
Development and Application of Materials
基金
国家自然基金(No.50674033)
博士后基金(No.2005037230)
关键词
成分梯度薄膜
热电
钒氧化物
组合激光溅射沉积技术
Composition-spread film
Thermoelectric
Vanadium oxide
Combinatorial Pulsed laser deposition