摘要
利用通道规律,并考虑了转动分布对跃迁峰型的影响,对测量得到的绝对氢分子光吸收谱进行了分析.文中逐个确定了110—150eV各振动态的振子强度,并得到了B′1Σ+u的解离强度.同时,利用多重散射Xα自洽场方法计算了氢分子分立区和连续区(110—190eV)的光吸收谱.通过计算值和实验绝对测量值的比较可以说明,在自洽层次。
Abstract By considering channel characters and thermal distribution of the
rotational levels, experimentally determined absolute photoabsorption spectrum of molecular
hydrogen have been analysed: these vibronic oscillator strengths in the region of 11 0 15 0eV
are determined, the total photodissociation of B′ 1Σ + u is also obtained. Meanwhile, the
photoabsorption spectrum in the valence and continuum regions (11 0 19 0eV) of molecular
hydrogen has been calculated based on multi scattering self consistent field. The theoretical
calculations are in good agreement with experimental results.
出处
《物理学报》
SCIE
EI
CAS
CSCD
北大核心
1999年第5期816-824,共9页
Acta Physica Sinica
基金
国家自然科学基金
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