摘要
Magnetic properties, phase evolution and microstructures of Pr9.44Fe90.56-xBx （x=7.16 and 4.76） nanocomposite magnets have been investigated. Both as-spun ribbons exhibit two-step demagnetization curves, indicating the feature of partial crystallization. By using di？erential scanning calorimeter （DSC） measurements, remained amorphous phase of ribbon with x=7.16 shows a higher crystallization temperature. At optimum annealing temperature of 650℃ for 10 min, better magnetic properties, Mr=1.01 T, jHc=796 kA/m and （BH）max=136 kJ/m3 were obtained in the sample with x=4.76. Transmission electron microscopy （TEM） observation confirms that the sample with x=4.76 possesses much finer grain size, which causing a better exchange coupling between soft and hard magnetic grains.
Magnetic properties, phase evolution and microstructures of Pr9.44Fe90.56-xBx （x=7.16 and 4.76） nanocomposite magnets have been investigated. Both as-spun ribbons exhibit two-step demagnetization curves, indicating the feature of partial crystallization. By using di？erential scanning calorimeter （DSC） measurements, remained amorphous phase of ribbon with x=7.16 shows a higher crystallization temperature. At optimum annealing temperature of 650℃ for 10 min, better magnetic properties, Mr=1.01 T, jHc=796 kA/m and （BH）max=136 kJ/m3 were obtained in the sample with x=4.76. Transmission electron microscopy （TEM） observation confirms that the sample with x=4.76 possesses much finer grain size, which causing a better exchange coupling between soft and hard magnetic grains.
基金
supported by the High Educational Talents Grant,Xi an University of Technology
Shaanxi Provincial Project of Special Foundation of Key Disciplines
Education Department of Shaanxi Provincial Government
